132356-06-0Relevant academic research and scientific papers
Novel reaction course of thiiranes to vinyloxiranes: Reaction of benzyne with thiiranes and aldehydes
Okuma, Kentaro,Qu, Yuxuan,Nagahora, Noriyoshi
, p. 1294 - 1300 (2021/07/19)
Reaction of 2 molar amount of 2-(trimethylsilyl)phenyl triflate with thiiranes and aldehydes in the presence of CsF afforded vinyloxiranes in one-pot operation. Reaction of benzyne with thiiranes gave the corresponding alkenyl phenyl sulfides, which furth
A FIRST EXAMPLE OF CATALYTIC YLIDE EPOXIDATION REACTION: FACILE SYNTHESIS OF VINYL EPOXIDES FROM ALDEHYDES CATALYZED BY DIISOBUTYL TELLURIDE
Zhou, Zhang-Lin,Shi, Li-Lan,Huang, Yao-Zeng
, p. 7657 - 7660 (2007/10/02)
In the presence of cesium carbonate, a variety of aldehydes can be epoxidized directly with allyl bromide at 50 deg C under solid-liquid phase transfer condition by use of a catalytic amount of diisobutyl telluride to afford vinyl epoxides in good yields
A Facile Synthesis of α,β-Unsaturated Epoxides via Allyldi-isobutyltelluronium Bromide
Zhou, Zhang-Lin,Sun, You-Shou,Shi, Li-Lan,Huang, Yao-Zeng
, p. 1439 - 1440 (2007/10/02)
In the presence of solid KOH, allyldi-isobutyltelluronium bromide 2 reacts directly with aromatic aldehydes at room temperature under solid-liquid phase-transfer conditions to afford α,β-unsaturated epoxides 3 in excellent yields.
