132365-49-2Relevant academic research and scientific papers
2-Trimethylsilylethyl-1,3-butadiene as a synthetic equivalent of parent cross-conjugated hexatriene, 3-methylene-1,4-pentadiene
Hosomi, Akira,Masunari, Toshiyuki,Tominaga, Yoshinori,Yanagi, Toshiharu,Hojo, Makoto
, p. 6201 - 6204 (1990)
2-Trimethylsilylethyl-1,3-butadiene, readily prepared by the cross-coupling reaction of the Grignard reagent of 3-bromo-3-butenyltrimethylsilane with vinyl bromide catalyzed by a nickel-phosphine complex, works as a synthetic equivalent to 3-methylene-1,4-pentadiene (parent [3]dendralene) by the consecutive Diels-Alder reactions.
