13238-43-2Relevant articles and documents
Improved Bimetallic Cobalt-Manganese Catalysts for Selective Oxidative Cleavage of Morpholine Derivatives
Leonard, David K.,Li, Wu,Junge, Kathrin,Beller, Matthias
, p. 11125 - 11129 (2019)
Catalytic methods for the site-selective scission of C(sp3)-C(sp3) bonds remain scarcely explored in contrast to the vast literature on C-C coupling. In view of this, we report a means of oxidative C-C single-bond cleavage in morphol
Visible-Light-Mediated Aerobic Oxidative C(sp3)?C(sp3) Bond Cleavage of Morpholine Derivatives Using 4CzIPN as a Photocatalyst
Dong, Chun-Lin,Huang, Lan-Qian,Guan, Zhi,Huang, Chu-Sheng,He, Yan-Hong
supporting information, p. 3803 - 3811 (2021/06/28)
Herein, a metal-free strategy for the aerobic oxidative cleavage of the inert C(sp3)?C(sp3) bond was developed. Deconstruction of morpholine derivatives was conducted using visible light as an energy source and O2 as an oxidant under mild conditions. This procedure demonstrated suitable selectivity and functional group tolerance. Moreover, a possible mechanism involving a radical process was proposed based on a series of mechanism exploration and control experiments. (Figure presented.).
Method for exciting C-C bond fracture acylation and application
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Paragraph 0034-0042, (2021/07/21)
The invention provides a method for exciting C-C bond breakage acylation and application; the method comprises the following steps: mixing a compound with a structural formula shown in the specification with an organic solvent, and reacting in oxygen and
Aerobic iron-catalyzed site-selective C(sp3)–C(sp3) bond cleavage in N-heterocycles
Beller, Matthias,Junge, Kathrin,Leonard, David K.,Li, Wu,Rockstroh, Nils
, (2021/06/26)
The kinetic and thermodynamic stability of C(sp3)–C(sp3) bonds makes the site-selective activation of these motifs a real synthetic challenge. In view of this, herein a site-selective method of C(sp3)–C(sp3) bon
