132381-00-1

Basic information

• Product Name: 5,5'-Bis(dicyanomethylene)-5,5'-dihydro-Δ^2,2'-bifuran
• CAS NO: 132381-00-1
• Molecular Weight: 260.211
• Mol File: 132381-00-1.mol

Chemical Properties

• CAS DataBase Reference: 5,5'-Bis(dicyanomethylene)-5,5'-dihydro-Δ^2,2'-bifuran(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5'-Bis(dicyanomethylene)-5,5'-dihydro-Δ^2,2'-bifuran(132381-00-1)
• EPA Substance Registry System: 5,5'-Bis(dicyanomethylene)-5,5'-dihydro-Δ^2,2'-bifuran(132381-00-1)

Safety Data

• Hazardous Substances Data: 132381-00-1(Hazardous Substances Data)

Upstream product

• 5905-00-0 2,2'-bifuran 

Relevant articles and documents

Novel electron acceptors bearing a heteroquinonoid system III: 2,5-Bis(dicyanomethylene)-2,5-dihydrofuran and its conjugated homologues as novel oxygen-containing electron acceptors

2,5-Bis(dicyanomethylene)-2,5-dihydrofuran with a 2,5-furanoquinonoid skeleton and its extensive conjugated homologues, 5,5′- bis(dicyanomethylene)-5,5′-dihydro-Δ2,2′-bifuran (8a), and 5,5″-bis(dicyanomethylene)-5,5″-dihydro-Δ 2,2′:5′,2″-terfuran (12a), have been prepared as a new type of oxygen-containing electron acceptors. In the synthetic course of the tetrabromo derivative of 12a, 3′,4-dibromo-5-(3,5-dibromo-2-furyl)-3, 5′bis(dicyanomethylene)-3,5′-dihydro-Δ2,2′- bifuran was also obtained as an unsymmetrical isomer possessing an unusual 2,3-furanoquinonoid conjugation, whose structure was confirmed on the basis of X-ray crystallography analysis. In addition, X-ray analysis of the TTF complex of 8a revealed that the bifuranoquinonoid conjugation has a trans form. These furanoquinonoid compounds behaved as weak electron acceptors, and accordingly failed to form conductive complexes. However, the 3,3′-dibromo derivative of 8a gave the TTT complex of a very high electrical conductivity.