132381-89-6Relevant articles and documents
Remarkable difference of chemoselectivity in the reduction of α-bromo ketones with dibutyltin dihydride system
Shibata, Ikuya,Nakamura, Kenji,Baba, Akio,Matsuda, Haruo
, p. 6381 - 6384 (1990)
Remarkably different chemoselectivities were noted in the reduction of α-bromo ketones by n-Bu2SnH2 system. Without additive, the reduction of α-bromo group took place. While, the addition of small amounts of p-Dinitrobenzene (DNB) caused the chemoselective reduction of carbonyl group.