13239-66-2

Basic information

• Product Name: triethyl(methyl)ammonium S-methyl carbonodithioate
• Synonyms: triethyl(methyl)ammonium S-methyl carbonodithioate
• CAS NO: 13239-66-2
• Molecular Weight: 223.404
• Mol File: 13239-66-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: triethyl(methyl)ammonium S-methyl carbonodithioate(CAS DataBase Reference)
• NIST Chemistry Reference: triethyl(methyl)ammonium S-methyl carbonodithioate(13239-66-2)
• EPA Substance Registry System: triethyl(methyl)ammonium S-methyl carbonodithioate(13239-66-2)

Safety Data

• Hazardous Substances Data: 13239-66-2(Hazardous Substances Data)

Upstream product

• 19708-81-7 methyl O-methyldithiocarbonate 
• 121-44-8 triethylamine 

Downstream Products

• 868-84-8 S,S-dimethyl dithiocarbonate 
• 37174-63-3 S-Methyl N,N-diethylthiocarbamate 

Relevant articles and documents

A facile, safe and inexpensive preparation of S -methyl arylcarbamothioates by methylthiocarbonylation of primary arylamines with O, S -dimethyl carbonodithioate

O,S-Dimethyl carbonodithioate is proposed as a suitable and safely handled reagent that can be used in the methylthiocarbonylation of primary arylamines to give S-methyl arylcarbamothioates. Optimal conditions involved a one-step procedure that was carried out at 45C in a solvent-free system, in the presence of triethyl(methyl)ammonium S-methyl carbonodithioate as a reaction promoter. The title products were obtained pure in yields that, with one exception, varied between 72 and 91% (average yield of the 12 considered examples was 83%). The by-product S,S-dimethyl carbonodithioate is also a valuable reagent. Georg Thieme Verlag Stuttgart · New York.