132409-35-9

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 917-54-4 methyllithium 
• 132409-30-4 [(E)-3-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-1-methyl-allyloxy]-tert-butyl-dimethyl-silane 
• 132409-30-4 [(Z)-3-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-1-methyl-allyloxy]-tert-butyl-dimethyl-silane 
• 115936-20-4 [(2S,3R)-3-[(benzyloxy)methyl]-2-methyloxiran-2-yl]methanol 
• 132409-29-1 (E)-4-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-but-3-en-2-ol 
• 132409-26-8 [3-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-1-methyl-prop-2-ynyloxy]-tert-butyl-dimethyl-silane 
• 132409-33-7 (5S,6R)-7-(Benzyloxy)-5,6-epoxy-5-methyl-3-hepten-2-one 
• 132409-28-0 (5S,6R)-7-(Benzyloxy)-5,6-epoxy-5-methyl-3-heptyn-2-one 
• 132409-22-4 (3S,4R)-5-(Benzyloxy)-1,1-dibromo-3,4-epoxy-3-methyl-1-pentene 
• 132409-25-7 4-((2S,3R)-3-Benzyloxymethyl-2-methyl-oxiranyl)-but-3-yn-2-ol 
• 132409-23-5 (3S,4R)-5-(Benzyloxy)-1-bromo-3,4-epoxy-3-methyl-1-pentyne 
• 115827-28-6 (2S,3R)-3-Benzyloxymethyl-2-methyl-oxirane-2-carbaldehyde 

Relevant academic research and scientific papers

Diastereodifferentiation in SN2' Additions of Methylcuprates to Nonracemic Acyclic Vinyloxiranes

SN2' additions of Me2CuLi, MeCu(CN)Li, and Me2Cu(CN)Li2 to the 2S and 2R alkoxy cis-(Z)- and -(E)-vinyloxiranes 8, 9, 13, and 14 were examined as possible routes to acyclic subunits of polypropionate natural products.Highest anti:syn ratios wer