132488-71-2

Basic information

• Product Name: (+)-Vinylboronic acid pinanediol ester
• Synonyms: (+)-Vinylboronic acid pinanediol ester
• CAS NO: 132488-71-2
• Molecular Formula: C12H19BO2
• Molecular Weight: 206.09
• Product Categories: Alkenyl;Boronate Esters;Boronic Acids and Derivatives
• Mol File: 132488-71-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• Density: 1.002 g/mL at 25 °C
• Refractive Index: n20/D 1.479
• Storage Temp.: 2-8°C
• CAS DataBase Reference: (+)-Vinylboronic acid pinanediol ester(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-Vinylboronic acid pinanediol ester(132488-71-2)
• EPA Substance Registry System: (+)-Vinylboronic acid pinanediol ester(132488-71-2)

Safety Data

• Hazardous Substances Data: 132488-71-2(Hazardous Substances Data)

Usage

Uses

(+)-Vinylboronic Acid Pinanediol Ester is used in the preparation of chiral allylboronate reagents for use in stereoselective allylboration of aldehydes.

Upstream product

• 230299-05-5 bis-(+)-pinanediolato diboron 
• 75927-49-0 pinacol vinylboronate 
• 6336-45-4 vinylboronic acid dibutyl ester 
• 22422-34-0 (1R,2R,3S,5R)-2,3-pinane diol 
• 3677-80-3 dichlorovinylborane 
• 4363-34-2 vinylboronic acid 
• 18680-27-8 pinanediol 

Relevant articles and documents

Optisch aktive Vinylboronate

The comparative synthesis of optical active vinylboronates starting with (-)-2,3-pinanediol (5) or (+)-diethyltartrate (7) and dichlorovinylborane (4a), vinylboronic acid (4c), and dibutyl vinylboronate (4d) is described.A new method for the synthesis of dihalovinylboranes 4a, 4b is presented.

The preparation of optically active boronic ester substituted Δ2-isoxazolines

In this paper we report our recent results in the area of nitrile oxide cycloaddition to optically active vinylboronic esters to afford optically active boronic ester substituted Δ2-isoxazolines. In these studies, a number of optically active d