13252-14-7Relevant academic research and scientific papers
2,4,4,5,7,7,8,8,9,9,9-Undecafluoro-2,5-bis(trifluoromethyl)-3, 6-dioxanonyl methacrylate
Paleta, Old?ich,Pale?ek, Ji?í,Michálek, Ji?í
, p. 51 - 53 (2002)
The title monomer (4) was prepared from the trimer of hexafluoropropene-1,2-oxide, 2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)- 3,6-dioxanonanoyl fluoride (1), via methyl ester 2 that was reduced by sodium borohydride to the corresponding alkanol 3, which was finally acylated by methacryloyl chloride.
Synthesis of novel perfluoroalkyl ether derivatives
Shi, Xiang,Shi, Hongxin,Wu, Hongke,Shen, HaiMin
, p. 5091 - 5105 (2018/04/05)
A series of novel fluoroether-containing monomers has been designed and prepared based on the commercially available perfluoroalkyl ether acid fluoride. Treating acid fluoride with allyl alcohol, 2-hydroxyethyl methacrylate or N-allylmethylamine allowed for the direct formation of corresponding vinyl-containing fluorinated monomers. High yields of the fluorinated epoxy monomers could be obtained from acid chloride with glycidol; meanwhile, fluorinated diol was prepared from diethanolamine or 3-amino-1,2-propanediol. Moreover, fluorinated monoamine, fluorinated monoalcohol and fluorinated dichloride were also obtained. Most of these fluorinated monomers were liquid at room temperature and exhibited good solubility in common organic solvents.
