1325219-89-3

Upstream product

• 1325219-88-2 1-bromo-4-fluoro-2-(2-nitrophenoxy)benzene 
• 1493-27-2 ortho-nitrofluorobenzene 
• 147460-41-1 2-bromo-5-fluorophenol 

Downstream Products

• 1325219-90-6 1-bromo-4-fluoro-2-(2-iodophenoxy)benzene 
• 1325219-91-7 ((2-(2-bromo-5-fluorophenoxy)phenyl)ethynyl)trimethylsilane 

Relevant academic research and scientific papers

Palladium-Catalyzed Synthesis of Six-Membered Benzofuzed Phosphacycles via Carbon-Phosphorus Bond Cleavage

The palladium-catalyzed synthesis of dibenzofused six-membered phosphacycles via carbon-phosphorus bond cleavage is developed. This method is compatible with a range of functional groups, such as esters, amides, and carbamates, which is in sharp contrast to the limitations of the classical method using organolithium reagents. (Figure Presented).

Synthesis and photochemical investigations of tetrasubstituted alkenes as molecular switches-the effect of substituents

Molecular switches based on helical tetrasubstituted alkenes, substituted with either electron-withdrawing (CF3, F, CN; 2 a-c, 3 a,c) or -donating substituents (Me, OMe; 2 d,e), have been synthesized from acyclic precursors 4 and 5 in a domino carbopalladation/Stille reaction. This palladium-catalyzed process allowed the rapid assembly of two C-C bonds, two six-membered rings, and the tetrasubstituted double bond in a completely diastereoselective fashion. The electronic effects of the substituents on the overall switching process were investigated by alternating irradiation of two different wavelength regions. Although the substituents had only a small influence on the absorption maxima, drastic differences in the switching behavior were observed. Copyright