1325449-37-3

Basic information

• Product Name: C₂₀H₂₄O₃P₂S
• Synonyms: C₂₀H₂₄O₃P₂S
• CAS NO: 1325449-37-3
• Molecular Weight: 406.422
• Mol File: 1325449-37-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₄O₃P₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₄O₃P₂S(1325449-37-3)
• EPA Substance Registry System: C₂₀H₂₄O₃P₂S(1325449-37-3)

Safety Data

• Hazardous Substances Data: 1325449-37-3(Hazardous Substances Data)

Upstream product

• 119713-39-2 5,5-dimethyl-2-oxo-2-(propa-1',2'-diene)-1,3,2-dioxaphosphorinane 
• 6591-07-7 diphenylphosphane sulfide 
• 119713-40-5 5,5-dimethyl-2-(1-propynyl)-2-oxo-1,3,2-dioxaphosphorinane 

Relevant articles and documents

Catalyst-free and catalysed addition of P(O)-H bonds to allenyl/alkynyl-phosphonates and-phosphane oxides: Use of a robust, recoverable dinuclear palladium(I) catalyst

An effective, recoverable, dinuclear palladium(I) catalyst [(OCH 2CMe2CH2O)PSPd(PPh3)]2 has been explored and compared with other traditional palladium catalysts (e.g., [Pd(PPh3)4]) in the phosphonylation/phosphanylation ofallenes (OCH2CMe2CH2O)P(O)CH=C=CH2 (1), Ph2P(O)CH=C=CH2 (2), (EtO)2P(O)CH=C= CH2 (3) (OCH2CMe2CH2O)P(O)CH=C= CMe2 (4), Ph2P(O)CH=C=CMe2 (5), (OCH 2CMe2CH2O)P(O)C(Ph)=C=CH2 (6) and Ph2P(O)C(Ph)=C=CH2 (7). The phosphonylation/ phosphanylation, in general, occurred at the carbon β to the phosphorus atom, but the concomitant proton addition took place at the α or γ positions leading to either allyl-or vinyl-phosphonates. The use of P(nBu) 3 as catalyst led to geminal and bis-phosphonylation/phosphanylation with less substituted =CH2 terminal allenes 1 and 2. In conjunction with the use of the corresponding isomeric alkynes 8 and 9, as many as five different types of phosphonylated products have been synthesized. The reactions with the more substituted allenes 4-7 gave single products in most cases. Several examples of catalyst-free, solvent-free phosphanylation reactions are also described. The reactivity of the phosphonylating/phosphanylating agents was found to be (OCH2CMe2CH2O)P(O)H (10) 2CMe2CH2O)P(S)H (11) 2P(O)H (12) ≈ Ph2P(S)H (13). The catalytic activity of the recoverable dinuclear palladium(I) complex [(OCH2CMe 2CH2O)PSPd(PPh3)]2 (14), which poses interesting questions about the mechanistic pathway, is briefly highlighted. Structures of the dinuclear palladium(I) catalyst 14 and the key products were determined by X-ray crystallography.