132559-62-7Relevant articles and documents
Syntheses of α,β-unsaturated carbonyl compounds from the reactions of monosubstituted ozonides with stable phosphonium ylides
Hon, Yung-Son,Lu, Ling,Chang, Rong-Chi,Lin, Sheng-Wun,Sun, Pei-Pei,Lee, Chia-Fu
, p. 9269 - 9279 (2007/10/03)
Ozonides derived from terminal alkenes reacted with 1.3 mol equiv. of stable phosphonium ylides to give (E)-αβ-unsaturated carbonyl compounds in good to excellent yields. No reducing agent is needed in the reaction. However, alkoxyalkyl-substituted ozonides afforded a mixture of (Z)- and (E)-αβ-unsaturated carbonyl compounds under similar condition. The E/Z isomeric ratio is affected by the position of the heteroatom in the substituent of the ozonides. The possible mechanism of this reaction will be discussed. (C) 2000 Elsevier Science Ltd.
Dienediolates from Unsaturated Carboxylic Acids: Michael Addition of Dilithium Buta-1,3-diene-1,1-diolate (from Crotonic Acid) to Unsaturated Ketones
Ballester, Pablo,Costa, Antonio,Raso, Angel Garcia,Gomez-Solivellas, Antonio,Mestres, Ramon
, p. 1711 - 1718 (2007/10/02)
Conjugate addition of the lithium dienediolate derived from crotonic acid to several α,β-unsaturated ketones gave 7-oxocarboxylic acids.Styryl ketones (2a-g) afforded mixtures of 1,4-α- and 1,4-γ-adducts, in proportions depending on the bulk of the substi
