1325592-64-0

Upstream product

• 109-04-6 2-bromo-pyridine 
• 62-53-3 aniline 
• 591-18-4 1-Bromo-3-iodobenzene 
• 6631-37-4 2-(phenylamino)pyridine 

Downstream Products

• 1325592-55-9 N-(3-(1H-pyrazol-1-yl)phenyl)-N-phenylpyridin-2-amine 
• 1325592-53-7 N-phenyl-N-(3-(pyridin-2-yl)phenyl)pyridin-2-amine 

Relevant academic research and scientific papers

ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANOMETALLIC COMPLEX FOR ORGANIC ELECTROLUMINESCENCE DEVICE

Provided is an organic electroluminescence device. The organic electroluminescence device according to an embodiment includes a first electrode, a second electrode facing the first electrode, and a plurality of organic layers between the first electrode and the second electrode, wherein at least one of the plurality of organic layers includes an organometallic complex including a metal atom which is a central atom, a plurality of ligand connected to the metal atom, and a nitrogen atom connecting two of the plurality of ligands. The nitrogen atom includes an aromatic ring group as a substituent. The aromatic ring group is not bonded to any of the plurality of ligands to form a ring, thereby allowing the organic electroluminescent device to exhibit a low drive voltage and improved life time.

Highly luminescent tridentate NC*N platinum(II) complexes featured in fused five-six-membered metallacycle and diminishing concentration quenching

A series of cyclometalating ligands, N-phenyl-N-(3-(pyridin-2-yl)phenyl) pyridin-2-amine (L1), N-(3-(1H-pyrazol-1-yl)phenyl)-N-phenylpyridin-2-amine (L2), N-phenyl-N-(3-(quinolin-2-yl)phenyl)pyridin-2-amine (L3), N-phenyl-N-(3-(pyridin-2-yl)phenyl)quinolin-2-amine (L4), N-(3-(isoquinolin-1- yl)phenyl)-N-phenylpyridin-2-amine (L5), and N-phenyl-N-(3-(pyridin-2-yl)phenyl) isoquinolin-1-amine (L6), were synthesized, which reacted with K 2PtCl4 in glacial acetic acid to produce NC*N-coordinated platinum(II) complexes featured in a fused five-six-membered metallacycle, 1-6, respectively. The structures of 1, 3, 4, and 6 were determined by single crystal X-ray crystallography. The square geometries of the complexes are improved when compared with those of the N^C^N-coordinated complexes as the bite angles for the platinum in N^C*N-coordinated complexes 1, 3, and 4 are increased. The Pt-C bonds (1.94-1.95 A) are shorter than those of C^N^N-coordinated platinum complexes but longer than those found for N^C^N-coordinated platinum complexes. With the increase of the steric interaction, the distortion of the molecules from a planar coordination geometry becomes more and more severe from 1 to 3 to 4 and 6, and in 6, the N-phenyl ring has to stand up on the coordination sphere to minimize the steric interaction with the N-isoquinolyl ring. The photophysical properties of the complexes were studied, and their absorption and emission spectra were interpreted by relating to the structural features revealed by the X-ray crystal structures and the orbital characters predicted by DFT calculations. All complexes are emissive in fluid at room temperature, and the quantum yields (up to 0.65) are comparable to those of highly emissive N^C^N-coordinated platinum complexes. Self-quenching was not observed in the concentration range of 10-6 to 10-4 M. Large rigidochromic shifts for the emissions of 2, 4, and 6 upon cooling from room temperature to rigid glass (77 K) were observed. Two different triplet states that control the emissions were proposed to account for the photophysical properties of 6.