1325593-76-7Relevant academic research and scientific papers
Ni-catalysed, domino synthesis of tertiary alcohols from secondary alcohols
Berini, Christophe,Navarro, Oscar
, p. 1538 - 1540 (2012/02/16)
The use of in situ generated (NHC)-Ni catalytic species (NHC = N-heterocyclic carbene) allows for the synthesis, in short reaction times, of a variety of tertiary alcohols from secondary alcohols through a domino oxidation-addition protocol.
Controlled alcohol-carbonyl interconversion by nickel catalysis
Maekawa, Takehisa,Sekizawa, Hiromi,Itami, Kenichiro
, p. 7022 - 7026 (2011/09/30)
All in one pot: A general synthetic platform allows the interconversion of alcohols and carbonyl compounds in a predictable and controlled fashion in one pot. Under the action of a Ni catalyst, PhCl, CsF, and arylboronates, several multistep alcohol-carbonyl interconversions have been achieved with good overall efficiency (see scheme). A one-pot nickel-catalyzed synthesis of flumecinol (a hepatic microsomal enzyme inducer) has also been demonstrated. Copyright
