132560-65-7Relevant academic research and scientific papers
A novel tandem arylsulfonylation and cyclization of arylazoxy aryl sulfones with norbornene catalyzed by a palladium(O) complex
Kamigata, Nobumasa,Satoh, Mayumi,Yoshida, Masato
, p. C26 - C29 (1991)
The reaction of arylazoxy aryl sulfones with norbornene in the presence of tetrakis(triphenylphosphine)palladium(O) was found to give cis, exo-2,3-norbornane-fused 2,3-dihydrobenzotiophene 1,1-dioxides in good yield.
NOVEL REACTION OF ARYLAZO ARYL AND ARYLAZOXY ARYL SULFONES WITH NORBORNENE CATALYZED BY A PALLADIUM(0) COMPLEX
Kamigata, Nobumasa,Satoh, Mayumi,Yoshida, Masato,Nakamura, Yoshihiro,Kikuchi, Koichi,Ikemoto, Isao
, p. 129 - 136 (2007/10/02)
The reactions of arylazo aryl sulfone and arylazoxy aryl sulfones with norbornene in the presence of a tetrakis(triphenylphosphine)palladium(0) were found to give cis,exo-1,2,3,4,4a,9b-hexahydro-1,4-methanodibenzothiophene 5,5-dioxides in good yield.The reaction mechanism involving aryl(arylsulfonyl)palladium(II) species as a common intermediate in both reactions is proposed.The result of an X-ray single crystal structure analysis of the novel reaction product is also described. Key words: Arylazo aryl sulfone; arylazoxy aryl sulfone; arylsulfonylation; X-ray diffraction.
