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1,3,5-tris(1H-pyrazol-4-yl)benzene, also known as TpB, is a chemical compound that features a benzene ring with three 1H-pyrazol-4-yl groups attached to it. 1,3,5-tris(1H-pyrazol-4-yl)benzene is widely recognized for its role as a ligand in coordination chemistry, especially within the realms of metal-organic frameworks (MOFs) and coordination polymers. TpB's capacity to form robust and stable bonds with metal ions is a testament to its versatility as a building block for crafting intricate supramolecular structures. Its distinctive structural and bonding attributes render TpB an indispensable resource for researchers in the quest to innovate new materials and catalysts, which could have far-reaching implications in sectors such as gas storage, catalysis, and sensing.

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  • 1325728-09-3 Structure
  • Basic information

    1. Product Name: 1,3,5-tris(1H-pyrazol-4-yl)benzene
    2. Synonyms:
    3. CAS NO:1325728-09-3
    4. Molecular Formula:
    5. Molecular Weight: 276.3
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1325728-09-3.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,3,5-tris(1H-pyrazol-4-yl)benzene(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,3,5-tris(1H-pyrazol-4-yl)benzene(1325728-09-3)
    11. EPA Substance Registry System: 1,3,5-tris(1H-pyrazol-4-yl)benzene(1325728-09-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1325728-09-3(Hazardous Substances Data)

1325728-09-3 Usage

Uses

Used in Coordination Chemistry:
1,3,5-tris(1H-pyrazol-4-yl)benzene is used as a ligand for [forming stable bonds with metal ions] due to [its ability to create strong, stable bonds with metal ions, contributing to the stability and functionality of metal-organic frameworks and coordination polymers].
Used in the Design of Metal-Organic Frameworks (MOFs):
1,3,5-tris(1H-pyrazol-4-yl)benzene is used as a building block for [constructing complex supramolecular structures] because of [its unique structure that allows for versatile interactions with metal ions, enhancing the design of MOFs with tailored properties].
Used in the Development of New Materials:
1,3,5-tris(1H-pyrazol-4-yl)benzene is used as a component in [creating new materials with potential applications in various fields] for [its contribution to the development of materials with specific properties, such as those needed for gas storage, sensing, or other specialized uses].
Used in Catalyst Design:
1,3,5-tris(1H-pyrazol-4-yl)benzene is used as a key element in [designing catalysts with enhanced performance] for [its role in forming active sites in catalysts, potentially improving their efficiency and selectivity in various chemical reactions].

Check Digit Verification of cas no

The CAS Registry Mumber 1325728-09-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,2,5,7,2 and 8 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1325728-09:
(9*1)+(8*3)+(7*2)+(6*5)+(5*7)+(4*2)+(3*8)+(2*0)+(1*9)=153
153 % 10 = 3
So 1325728-09-3 is a valid CAS Registry Number.

1325728-09-3Downstream Products

1325728-09-3Relevant articles and documents

Preparation method of pyrazole-4-aryl derivative

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Paragraph 0019, (2019/01/07)

The invention discloses a preparation method of a pyrazole-4-aryl derivative. The preparation method comprises the following step: mixing an aryl halide derivative, a pyrazole-4-boronic acid pinacol ester derivative, first alkali, a first phase transfer catalyst and a first palladium-based catalyst in a first solvent to carry out reaction so as to prepare the pyrazole-4-aryl derivative. Through the manner, the pyrazole-4-aryl derivative is prepared through the adoption of a one-pot method; the reaction condition is mild and the post-treatment is simple and convenient, so that the method is suitable for multiple aryl halide derivatives, strong in operability and suitable for industrial production; and the obtained pyrazole compound can be widely applied to the field of chemical engineering,medicines, biology and materials.

Efficient and chromatography-free methodology for the modular synthesis of oligo-(1H-pyrazol-4-yl)-arenes with controllable size, shape and steric bulk

Kershaw Cook, Laurence J.,Kearsey, Rachel,Lamb, Jessica V.,Pace, Edward J.,Gould, Jamie A.

supporting information, p. 895 - 898 (2016/02/05)

A novel methodology to synthesise oligo-(1H-pyrazol-4-yl)-arenes with controllable size, shape and steric bulk from 1-trityl-1H-pyrazol-4-ylboronate pinacol esters. This straightforward and efficient procedure can be applied to a variety of brominated aro

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