1325730-34-4Relevant articles and documents
An efficient copper(I)-catalyst system for the asymmetric hydroboration of β-substituted vinylarenes with pinacolborane
Noh, Dongwan,Yoon, Sue Kyoung,Won, Jiyeon,Lee, Jin Yong,Yun, Jaesook
supporting information; scheme or table, p. 1967 - 1969 (2011/10/31)
The pinacol of ligands: The (R)-DTBM-Segphos coordinated copper(I) complex was found to be very effective for the asymmetric hydroboration of β-substituted styrene derivatives with pinacolborane (see scheme; DTBM=3,5-di-tert-butyl-4-methoxyphenyl). This new method affords benzylic pinacol boronate esters with excellent levels of regio- and enantioselectivity (>99 %).