1325764-05-3Relevant articles and documents
Efficient synthesis of diborylalkenes from alkenes and diboron by a new PSiP-pincer palladium-catalyzed dehydrogenative borylation
Takaya, Jun,Kirai, Naohiro,Iwasawa, Nobuharu
, p. 12980 - 12983 (2011)
The efficient synthesis of various diborylalkenes such as 1,1-, trans-1,2-, and cyclic 1,2-diborylalkenes from alkenes and diboron was achieved for the first time. Selective preparation of di- and monoborylalkenes was also realized by the appropriate choi
PSiP-pincer type palladium-catalyzed dehydrogenative borylation of alkenes and 1,3-Dienes
Kirai, Naohiro,Iguchi, Shoichiro,Ito, Tatsuyoshi,Takaya, Jun,Iwasawa, Nobuharu
, p. 784 - 799 (2013/08/23)
Dehydrogenative borylation of alkenes and 1,3-dienes was realized by carrying out the reaction in the presence of bis(pinacolato)diboron (B2pin2) and a catalytic amount of PSiP-pincer palladium complex. This protocol has the following notable features. 1)