132587-11-2

Basic information

• Product Name: 1-(2,4-dichlorophenyl)-3-buten-1-yl acetate
• CAS NO: 132587-11-2
• Molecular Weight: 259.132
• Mol File: 132587-11-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(2,4-dichlorophenyl)-3-buten-1-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2,4-dichlorophenyl)-3-buten-1-yl acetate(132587-11-2)
• EPA Substance Registry System: 1-(2,4-dichlorophenyl)-3-buten-1-yl acetate(132587-11-2)

Safety Data

• Hazardous Substances Data: 132587-11-2(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 874-42-0 2,4-dichlorobenzaldeyhde 
• 106-95-6 allyl bromide 
• 13086-94-7 1,1-diacetoxy-1-(2,4-dichlorophenyl)methane 
• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 132587-14-5 (+)-1-(2,4-dichlorophenyl)-3-buten-1-ol 
• 132587-14-5 (-)-1-(2,4-dichlorophenyl)-3-buten-1-ol 

Relevant articles and documents

Indium-mediated one-pot, three-component synthesis of homoallyl alcohol esters without catalysts and dehydrants

Indium-mediated one-pot esterification reaction of acyl chlorides or anhydride by using in situ-prepared homoallyl alcohols from aromatic aldehydes and allyl bromide proceeded smoothly to afford the corresponding homoallyl alcohol esters in high yields within about 1 h, which provided a simple and efficient protocol for the simultaneous allylation and esterification of aldehydes without other catalysts and dehydrants.

Indium(III) chloride catalyzed allylation of gem-diacetates: A facile synthesis of homoallyl acetates

Indium(III) chloride is found to catalyze efficiently the allylation of gem-diacetates with allyltrimethylsilane at room temperature to afford the corresponding homoallylic acetates in high yields with good regioselectivity.