132610-91-4

Upstream product

• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 1027539-53-2 (S)-5-Isopropenyl-1-(4-methoxy-phenyl)-2-methyl-cyclohex-2-enol 
• 13139-86-1 4-methoxyphenyl magnesium bromide 

Downstream Products

• 132611-06-4 (S)-8-Methoxy-6-(4-methoxy-phenyl)-1,8-dimethyl-bicyclo[2.2.2]oct-5-en-2-one 
• 132610-87-8 4-Bromo-7-(4-methoxy-phenyl)-1,5-dimethyl-bicyclo[3.2.1]oct-6-en-2-one 
• 132610-83-4 (S)-8-Bromo-6-(4-methoxy-phenyl)-1,8-dimethyl-bicyclo[2.2.2]oct-5-en-2-one 
• 132610-79-8 (2S,6S,7S)-6-(4-Methoxy-phenyl)-1,5-dimethyl-tricyclo[3.2.1.0^2,7]octan-4-one 
• 132610-98-1 (5R)-5-(1-Bromo-2-methoxypropan-2-yl)-3-(4-methoxyphenyl)-2-methylcyclohex-2-enone 

Relevant academic research and scientific papers

Synthesis of chiral bicyclo [2.2.2] oct-5-en-2-ones via an intramolecular alkylation reaction

Generation of the thermodynamic dienolate of 9-bromocarvone derivatives 5,7 and 11 furnished the chiral bicyclo[2.2.2]octenones 6, 8 and 9 and 12 and 13 containing a bridgehead methyl group via an intramolecular alkylation reaction. In an analogous manner

Cyclopropanes via an Efficient 3-Exo Trig Radical Cyclisation Reaction

The first examples of an exclusive formation of a cyclopropane via the 3-exo trig radical cyclisation of homoallyl bromides 13 and 14 are reported.