132619-16-0

Basic information

• Product Name: (2S,4S)-2-[(R)-1-Benzenesulfonylmethyl-4-(tetrahydro-pyran-2-yloxy)-but-2-ynyl]-4-isopropyl-oxazolidine-3-carboxylic acid benzyl ester
• CAS NO: 132619-16-0
• Molecular Weight: 555.692
• Mol File: 132619-16-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,4S)-2-[(R)-1-Benzenesulfonylmethyl-4-(tetrahydro-pyran-2-yloxy)-but-2-ynyl]-4-isopropyl-oxazolidine-3-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4S)-2-[(R)-1-Benzenesulfonylmethyl-4-(tetrahydro-pyran-2-yloxy)-but-2-ynyl]-4-isopropyl-oxazolidine-3-carboxylic acid benzyl ester(132619-16-0)
• EPA Substance Registry System: (2S,4S)-2-[(R)-1-Benzenesulfonylmethyl-4-(tetrahydro-pyran-2-yloxy)-but-2-ynyl]-4-isopropyl-oxazolidine-3-carboxylic acid benzyl ester(132619-16-0)

Safety Data

• Hazardous Substances Data: 132619-16-0(Hazardous Substances Data)

Upstream product

• 132556-08-2 (2S,4S)-2-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-4-isopropyl-oxazolidine-3-carboxylic acid benzyl ester 
• 37566-51-1 (3-tetrahydropyran-2-yloxy-prop-1-ynyl)-lithium 

Relevant articles and documents

Asymmetric Synthesis via Heteroconjugate Addition: Valinol Template as Oxazolidine Heteroolefin vs Acetylenic Nucleophiles

The diastereoselective C-C bond forming reaction via heteroconjugate addition strategy was expanded for asymmetric synthesis.A valinol derivative was employed as chiral template to induce chelation control in the heteroconjugate addition of alkyls and alk