1326317-61-6Relevant articles and documents
Copper-catalyzed β-boration of α,β-unsaturated carbonyl compounds with tetrahydroxydiborane
Molander, Gary A.,McKee, Silas A.
, p. 4684 - 4687 (2011/11/06)
The copper-catalyzed β-boration of α,β-unsaturated carbonyl compounds with tetrahydroxydiborane has been developed. This diboron reagent allows direct, efficient access to boronic acids and their derivatives. Primary, secondary, and tertiary α,β-unsaturated amides are converted to the corresponding β-trifluoroboratoamides in good to excellent yields. The β-boration of a variety of α,β-unsaturated esters and ketones is also reported.
