132653-29-3Relevant academic research and scientific papers
1,5 Allylic abstraction, cyclisation: A new route to five membered carbocycles
Borthwick,Caddick,Parsons
, p. 6911 - 6914 (1990)
A new 1,5 allylic abstraction cyclisation sequence has been developed. The method is based upon a novel radical rearrangement and is applicable to the construction of highly functionalised cyclopentanoid ring systems.
The Organic Synthesis Using Haloboration Reaction 20. A Simple Synthesis of (2-Bromoallyl)diphenoxyborane by the Bromoboration of Allene and its Reaction with Carbonyl Compounds
Hara, Shoji,Suzuki, Akira
, p. 6749 - 6752 (1991)
Bromoboration reaction of allene with boron tribromide, followed by the treatment with anisole gives (2-bromoallyl)diphenoxyborane which reacts with aldehydes and ketones to give 2-bromohomoallylic alcohols in excellent yields.
APPROACHES TO BICYCLIC RING SYSTEMS VIA 1,5 ALLYLIC ABSTRACTION CYCLISATION
Borthwick, A. D.,Caddick, S.,Parsons, P. J.
, p. 10655 - 10666 (2007/10/02)
A new 1,5 allylic abstraction, cyclisation sequence has been developed and applied to the synthesis of fused bicyclic systems.Initial studies directed towards the synthesis of the bicyclooctane skeleton are described: vinyl bromide 4 was subjected
