13269-86-8

Usage

Uses

Used in Pharmaceutical Industry:
1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene is used as a key intermediate in the synthesis of pharmaceutical compounds for its unique reactivity and ability to form new molecular structures.
Used in Polymer Industry:
In the polymer industry, 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene is used as a monomer or a component in the production of polymers with specific properties, such as enhanced stability and chemical resistance.
Used in Agrochemical Industry:
1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene is employed as a precursor in the development of agrochemicals, where its unique chemical properties can contribute to the creation of effective and targeted products.
It is crucial to handle and store 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene with care due to its potential hazardous properties, necessitating special handling and storage protocols to ensure safety.

Synthetic route

1,2,2,2-tetrafluoroethyl ether (67429-44-1) + methyllithium (917-54-4) → perfluorovinyl ether (13269-86-8) + C5H6F6O + 1,2,2,2-tetrafluoroethyl 1,2,2-trifluoroethenyl ether (1251167-61-9)

Conditions	Yield
In formaldehyde diethyl acetal at -36 - -15℃; Product distribution / selectivity; Inert atmosphere;

perfluorovinyl ether (13269-86-8) + di-(perfluoro vinyl) chloro borane (669-89-6) → (F2CCF)2BCl*O(F2CCF)2

Upstream product

• 67429-44-1 1,2,2,2-tetrafluoroethyl ether 
• 917-54-4 methyllithium 

Relevant academic research and scientific papers

METHODS FOR PREPARING FLUORINATED VINYL ETHERS

A method for preparing a fluorinated vinyl ether compound comprising reacting a fluorinated ether substrate having (i) a hydrogen atom on a carbon atom that is alpha to an etheric oxygen and (ii) a fluorine atom on a carbon atom that is beta to the etheric oxygen, with an organolithium base to provide a reaction product comprising a fluorinated vinyl ether compound.

Reactive compounds containing perfluorocyclobutane rings

Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: STR1 wherein R and R' independently represent optionally inertly substituted groups; X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compound are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula I wherein G represents G or G' in Formula II; X represents X or X' of Formual II; and n represents n or n' of Formula II, to form a compound having a perfluorocyclobutane group.

Perfluorovinyl compounds

Compounds have a structure represented by Formula I: wherein R represents an unsubstituted or inertly substituted hydrocarbyl group; each X is independently selected from the group consisting of groups having at least one non-carbon atom between R and --CF=CF2 ; and m is an integer of from 1 to about 3. Polymers formed from such compounds are also prepared. The compounds are preferably prepared by a method by a process comprising the steps of: (a) forming a salt having anion corresponding to a compound of Formula II: wherein X, R and m are as defined for Formula I; (b) reacting the salt with a 1,2-dihalo-1,1,2, 2-tetrafluoroethane wherein the halo groups are iodine, bromine, chlorine or mixtures thereof, at least one halo group being bromine or iodine, to form a compound of Formula III: wherein X, R and m are as defined for Formula I and each Z is independently iodine or bromine; (c) eliminating the halogen atoms represented by Z to form the perfluorovinyl compound represented by Formula I.

β-Substituted polyfluoropropionate salts and derivatives

β-substituted polyfluoropropionate salts, derivatives and copolymers and processes for the preparation thereof.

Fluorine containing ketones

By reaction of a perfluoro vinyl ether with a perfluoro carbonic acid fluoride perfluorinated ketones of the formula R1 --O--CF(CF3)--CO--R2 with at least 13 carbon atoms may be obtained. These ketones may be used as inert solvents of high boiling point. The reaction is catalyzed by cesium fluoride and carried out in an aprotic polar solvent.