1327004-69-2Relevant academic research and scientific papers
On the configurational stability of α-lithiated sulfurated styrene oxides: Synthetic and mechanistic aspects
Capriati, Vito,Dammacco, Mariangela,Florio, Saverio,Perna, Filippo M.,Salomone, Antonio
, p. 1274 - 1277 (2011/09/15)
The configurational stability of some sulfurated styrene oxides has been investigated. Chemical studies have shown that in THF at 157 K α-lithiated ortho-and paraphenylthiostyrene oxides are configurationally unstable and undergo a fast racemization on the time scale of the reaction, whereas α-lithiated meta-phenylthiostyrene oxide retains its stereochemical integrity for at least 60 min. The deprotonation-trapping methodology has also been employed for the preparation of a sulfurated β-aminoalcohol effective for the fight against phytopathogenic fungi. Copyright Taylor and Francis Group, LLC.
