132716-05-3

Basic information

• Product Name: (E)-4-benzoyloxy-1-iodo-1-butene
• Synonyms: (E)-4-benzoyloxy-1-iodo-1-butene
• CAS NO: 132716-05-3
• Molecular Weight: 302.112
• Mol File: 132716-05-3.mol

Chemical Properties

• CAS DataBase Reference: (E)-4-benzoyloxy-1-iodo-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-benzoyloxy-1-iodo-1-butene(132716-05-3)
• EPA Substance Registry System: (E)-4-benzoyloxy-1-iodo-1-butene(132716-05-3)

Safety Data

• Hazardous Substances Data: 132716-05-3(Hazardous Substances Data)

Upstream product

• 884864-15-7 benzoic acid (Z)-4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)but-3-enyl ester 

Downstream Products

• 856410-62-3 Benzoic acid (E)-(7R,9R)-7-(tert-butyl-dimethyl-silanyloxy)-10-(4-methoxy-benzyloxy)-9-methyl-5-oxo-dec-3-enyl ester 
• 856410-63-4 Benzoic acid (E)-(5R,7R,9R)-7-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-10-(4-methoxy-benzyloxy)-9-methyl-dec-3-enyl ester 
• 856410-44-1 Benzoic acid (E)-(5R,7R,9R)-5,7-dihydroxy-10-(4-methoxy-benzyloxy)-9-methyl-dec-3-enyl ester 
• 856410-45-2 Benzoic acid 2-{(2R,6S)-6-[(R)-3-(4-methoxy-benzyloxy)-2-methyl-propyl]-5,6-dihydro-2H-pyran-2-yl}-ethyl ester 
• 856410-43-0 Benzoic acid (E)-(7R,9R)-7-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-10-(4-methoxy-benzyloxy)-9-methyl-dec-3-enyl ester 

Relevant articles and documents

E / Z -Selectivity Controlled by Participation of Internal Oxy Group during Electrophilic Substitution of Alk-1-enylboronate with Bis(2,4,6-trimethylpyridine)iodonium Salt

Stereospecific inversion of configuration was observed in electrophilic iodo-substitution of 4-benzoyloxybut-1-enylboronate using bis(2,4,6-trimethylpyridine)iodine(I) salt, rationalized by participation of the internal benzoyloxy group.