132755-69-2

Basic information

• Product Name: methyl N-<4-nitro-2-(phthalimidomethyl)phenyl>carbamate
• Synonyms: methyl N-<4-nitro-2-(phthalimidomethyl)phenyl>carbamate
• CAS NO: 132755-69-2
• Molecular Weight: 355.307
• Mol File: 132755-69-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl N-<4-nitro-2-(phthalimidomethyl)phenyl>carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N-<4-nitro-2-(phthalimidomethyl)phenyl>carbamate(132755-69-2)
• EPA Substance Registry System: methyl N-<4-nitro-2-(phthalimidomethyl)phenyl>carbamate(132755-69-2)

Safety Data

• Hazardous Substances Data: 132755-69-2(Hazardous Substances Data)

Upstream product

• 118-29-6 2-(hydroxymethyl)-1H-isoindole-1,3(2H)-dione 
• 1943-87-9 methyl N-(4-nitrophenyl)carbamate 
• 100-01-6 4-nitro-aniline 
• 132755-73-8 methyl N-(4-nitrophenyl)-N-(phthalimidomethyl)carbamate 

Relevant articles and documents

The Phthalimidomethyl Rearrangement

The discovery of a new acid-catalysed monodentate N -> C aromatic rearrangement, namely the phthalimidomethyl rearrangement, is reported.In this rearrangement, discovered during the reaction of N-hydroxymethylphthalimide with certain alkyl N-(4-nitrophenyl)carbamates in concentrated sulfuric acid solution, the phthalimidomethyl group migrates from its initial location on the nitrogen atom of the carbamate function to a carbon atom of the nitrophenyl group.Evidence, provided by an appropriate 'crossover' experiment, indicates that the rearrangement is intermolecular.Hindered rotation about the N(carbamoyl)-aryl bond of the N-phthalimidomethyl derivatives of both ethyl and methyl N-(2,4-dinitrophenyl)carbamate is reported.