132771-52-9Relevant academic research and scientific papers
A novel synthesis of tetramesityldisilene
Chiappe, Cinzia,Imperato, Giovanni,Lenoir, Dieter,Napolitano, Elio
, p. 8893 - 8895 (2006)
Dimesityldiclorosilane undergoes reductive coupling with potassium-graphite to afford a mixture of cyclic polysilanes in a high yield and purity; this mixture is quantitatively converted to the title compound by photochemical irradiation.
Isolable 1,1-disubstituted silole dianion: A homogeneous two-electron-transfer reducing reagent
Han, Zhengang,Li, Jianfeng,Hu, Hongfan,Zhang, Jianying,Cui, Chunming
, p. 5890 - 5892 (2014)
The 1,1-disubstituted silole dianion 2 has been isolated and characterized by single-crystal X-ray analysis for the first time. 2 can be used as a two-electron-transfer reducing reagent for the reduction of organic compounds and inorganic salts with regeneration of the corresponding neutral silole in nearly quantitative yields, indicating that it is an excellent reducing reagent. Reduction of (Mes)2SiCl2 with 2 selectively yielded the cyclotrisilane (Mes2Si)3 in high yield, which has not been isolated in pure form with the existing methods.
