132771-55-2Relevant academic research and scientific papers
Molecular Interactions of Polysilane and Unsaturated Nitrogen Compounds. Photochemical Addition of Disilene versus Silylene to Azobenzene
Sakakibara, Akihito,Kabe, Yoshio,Shimizu, Toshio,Ando, Wataru
, p. 43 - 44 (2007/10/02)
Photochemical reaction of hexamesitylcyclotrisilane 1 or tetramesityldisilene 2 with azobenzene produces silanol 5 via hydrolysis of diazasilacyclopropane 3 and/or 1,2-diaza-3,4-disilacyclobutane 4; the structure of 4 has been confirmed by variable temperature 1H NMR spectroscopy and single-crystal X-ray diffraction, the existence of an Si2N2 ring system is demonstrated.
