132819-77-3Relevant academic research and scientific papers
Mechanistic Insights into the Post-Cyclization Isomerization in Gold-Catalyzed 7-exo-dig-Hydroarylations
Pfl?sterer, Daniel,Schumacher, S?ren,Rudolph, Matthias,Hashmi, A. Stephen K.
, p. 11585 - 11589 (2015)
The subsequent double-bond isomerization in the synthesis of dibenzocycloheptenes and their heteroaromatic analogues was investigated. In the case of biphenyls, a basic additive completely prevented an isomerization to the thermodynamic product. With elec
STEREOSELECTIVE SYNTHESIS OF 1-INDANYLIDENE SUBSTITUTED HETEROAROMATIC DERIVATIVES VIA Pd-CATALYZED TANDEM INSERTION AND CROSS COUPLING REACTIONS
Luo, Fen-Tair,Wang, Ren-Tzong
, p. 1543 - 1548 (2007/10/02)
Treatment of 4-(o-iodophenyl)-1-butyne with variety of heteroarylzinc chlorides in the presence of catalytic amount of Pd(PPh3)4, gave (Z)-1-indanylidene substituted heteroaromatics in moderate to good yields with high Z-selectivities.
