132853-79-3

Basic information

• Product Name: (E)- and (Z)-2-methoxymethylene-9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonane
• CAS NO: 132853-79-3
• Molecular Weight: 321.441
• Mol File: 132853-79-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)- and (Z)-2-methoxymethylene-9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)- and (Z)-2-methoxymethylene-9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonane(132853-79-3)
• EPA Substance Registry System: (E)- and (Z)-2-methoxymethylene-9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonane(132853-79-3)

Safety Data

• Hazardous Substances Data: 132853-79-3(Hazardous Substances Data)

Upstream product

• 107970-41-2 ethyl 2-(p-tolylsulphonylamino)hepta-5,6-dienoate 
• 111964-04-6 cis-(p-tolylsulphonyl)-5-vinylproline ethyl ester 
• 111964-05-7 cis 2-(2-bromoethyl)-5-<(methylsulphonyl)acetyl>-1-(p-tolylsulphonyl)pyrrolidine 
• 133038-55-8 cis-2-(2-hydroxyethyl)-1-(p-tolylsulphonyl)-5-<(methylsulphonyl)acetyl>pyrrolidine 
• 111964-06-8 3-(methylsulphonyl)-9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonan-2-one 
• 133038-54-7 cis-5-(2-hydroxyethyl)-1-(p-tolylsulphonyl)proline ethyl ester 
• 111964-07-9 9-(p-tolylsulphonyl)-9-azabicyclo<4.2.1>nonan-2-one 
• 112009-95-7 cis-1-(t-butoxycarbonyl)-5-vinylproline ethyl ester 
• 112009-91-3 ethyl 2-(t-butoxycarbonylamino)hepta-5,6-dienoate 
• 112009-90-2 ethyl 2-benzylideneaminohepta-5,6-dienoate 
• 133038-50-3 cis-1-methoxycarbonyl-5-vinylproline ethyl ester 
• 133038-46-7 ethyl 2-(methoxycarbonylamino)hepta-5,6-dienoate 
• 112009-96-8 cis-5-vinylproline ethyl ester 
• 112009-92-4 ethyl 2-aminohepta-5,6-dienoate 

Downstream Products

• 64314-16-5 (+/-)-anatoxin-a 
• 90741-53-0 t-butyl-1-(9-azabicyclo<4.2.1>-non-2-ene-2-yl)ethanone carbamate 
• 111964-12-6 t-butyl 2-formyl-9-azabicyclo<4.2.1>non-2-ene-9-carboxylate 

Relevant articles and documents

Synthetic and Stereochemical Studies Directed Towards Anatoxin-a

The synthesis and stereocontrolled Ag1-catalysed cyclisation of a series of allenic amino esters 8a-e is described.For compounds 8a-d the cis-2,5-disubstituted pyrrolidine 9 is formed exclusively but the primary amine 8e undergoes cyclisation n