132856-34-9 Usage
Common Use
Reagent in organic synthesis
Application
Grignard reactions
Reaction Type
Addition reaction to carbonyl group
Function
Forms new carbon-carbon bonds
Versatility
Can synthesize various organic compounds
Reactivity
High reactivity
Selectivity
Known for its selectivity
Importance
Essential for complex organic molecule synthesis
Check Digit Verification of cas no
The CAS Registry Mumber 132856-34-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,2,8,5 and 6 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 132856-34:
(8*1)+(7*3)+(6*2)+(5*8)+(4*5)+(3*6)+(2*3)+(1*4)=129
129 % 10 = 9
So 132856-34-9 is a valid CAS Registry Number.
InChI:InChI=1/C10H13.ClH.Mg/c1-7-5-8(2)10(4)9(3)6-7;;/h5-6H,4H2,1-3H3;1H;/q;;+1/p-1/rC10H13ClMg/c1-7-4-8(2)10(6-12-11)9(3)5-7/h4-5H,6H2,1-3H3
132856-34-9Relevant articles and documents
Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C-O Bond Cleavage
Tobisu, Mamoru,Takahira, Tsuyoshi,Chatani, Naoto
, p. 4352 - 4355 (2015)
Nickel-catalyzed cross-coupling of methoxyarenes with alkyl Grignard reagents, which involves the cleavage of the C(aryl)-OMe bond, has been developed. The use of 1,3-dicyclohexylimidazol-2-ylidene as a ligand allows the introduction of a variety of alkyl groups, including Me, Me3SiCH2, ArCH2, adamantyl, and cyclopropyl. The method can also be used for the alkylative elaboration of complex molecules bearing a C(aryl)-OMe bond.
