132859-10-0

Basic information

• Product Name: C₁₃H₁₈O
• CAS NO: 132859-10-0
• Molecular Weight: 190.285
• Mol File: 132859-10-0.mol

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₈O(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₈O(132859-10-0)
• EPA Substance Registry System: C₁₃H₁₈O(132859-10-0)

Safety Data

• Hazardous Substances Data: 132859-10-0(Hazardous Substances Data)

Upstream product

• 141-79-7 4-methyl-pent-3-en-2-one 
• 6921-34-2 benzylmagnesium chloride 

Relevant articles and documents

Influence of geminal disubstitution on samarium diiodide induced reductive cyclizations of γ-aryl ketones

Geminal disubstitution at the alkyl chain of γ-aryl ketones significantly influences the efficacy of samarium diiodide induced cyclizations providing significantly higher yields. β,β-Disubstituted aryl ketones 11a-e and γ,γ-disubstituted aryl ketone 14 could be converted into the corresponding hexahydronaphthalene derivatives in good yields. On the other hand, α,α-disubstituted ketone 9 only gave the secondary alcohol 10 along with recovered starting material. Aryl ketones containing substituents with hetero-atoms could also be cyclized in high yields and substrates such as 11d with sterically demanding cyclic substituents efficiently afforded spiro compounds. Georg Thieme Verlag Stuttgart.