13288-64-7Relevant articles and documents
Reactivity of 2-methyl thioisomünchnone with acid chlorides
ávalos, Martín,Babiano, Reyes,Cintas, Pedro,Díaz, Jesús,Hursthouse, Michael B.,Jiménez, José L.,Light, Mark E.,López, Ignacio,Palacios, Juan C.
, p. 4657 - 4660 (2003)
This work describes the reactivity of 2-alkyl thioisomünchnones, exemplified here by the 2-methyl derivative, which behaves as nucleophile in the presence of both aliphatic and aromatic acid chlorides to give 2-heteroaryl ketones or 2-heteroaryl-1,3-diketones, respectively. However, 2-alkyl thioisomünchnones exhibit its characteristic 1,3-dipole behavior toward unsaturated systems.