132883-11-5

Basic information

• Product Name: (S)-6-Methyl-1,4-dioxa-spiro[4.5]decane
• Synonyms: (S)-6-Methyl-1,4-dioxa-spiro[4.5]decane
• CAS NO: 132883-11-5
• Molecular Weight: 156.225
• Mol File: 132883-11-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-6-Methyl-1,4-dioxa-spiro[4.5]decane(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-6-Methyl-1,4-dioxa-spiro[4.5]decane(132883-11-5)
• EPA Substance Registry System: (S)-6-Methyl-1,4-dioxa-spiro[4.5]decane(132883-11-5)

Safety Data

• Hazardous Substances Data: 132883-11-5(Hazardous Substances Data)

Upstream product

• 115431-90-8 1-(per-O-methyl-β-D-glucopyranosyloxy)-1,4-cyclohexadiene 
• 132840-96-1 (S)-6-Methyl-1,4-dioxa-spiro[4.5]dec-7-ene 

Downstream Products

• 22554-27-4 (S)-2-methylcyclohexanone 

Relevant articles and documents

REGIO- AND STEREOSELECTIVE CONTROL IN THE ALKYLATION OF 1-ALKOXY-1,4-CYCLOHEXADIENES BY THE CHIRAL AUXILIARY APPROACH. ENANTIOSELECTIVE SYNTHESIS OF PRECURSORS FOR CIS-HYDRINDANES.

A method is described for the regio- and diastereoselective alkylation of optically active 1-alkoxy-1,4-cyclohexadienes.Reaction conditions were optimised for substrates 4a with the per-O-methyl-β-D-glucopyranosyl group as chiral auxiliary.In the methylat