132910-67-9

Basic information

• Product Name: Proline, 1-(2-propenyl)-, methyl ester (9CI)
• Synonyms: Proline, 1-(2-propenyl)-, methyl ester (9CI);METHYL 1-(PROP-2-EN-1-YL)PYRROLIDINE-2-CARBOXYLATE
• CAS NO: 132910-67-9
• Molecular Formula: C₉H₁₅NO₂
• Molecular Weight: 169.2209
• Product Categories: PYRROLE
• Mol File: 132910-67-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Proline, 1-(2-propenyl)-, methyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Proline, 1-(2-propenyl)-, methyl ester (9CI)(132910-67-9)
• EPA Substance Registry System: Proline, 1-(2-propenyl)-, methyl ester (9CI)(132910-67-9)

Safety Data

• Hazardous Substances Data: 132910-67-9(Hazardous Substances Data)

Upstream product

• 2133-40-6 methyl pyrrolidine-2-carboxylate hydrochloride 
• 106-95-6 allyl bromide 
• 609-36-9 rac-Pro-OH 

Downstream Products

• 124852-83-1 1-benzoyl-1,1a,3,3a-tetrahydropyrrolizidino<3,2-c>isoxazole 

Relevant articles and documents

Thermally Induced Intramolecular Oxime Olefin Cycloadditions (IOOC) Leading to N-Bridgehead Systems. Stereochemistry and Molecular Mechanics Calculations

The intramolecular oxime olefin cycloaddition (IOOC) of proline and pipecolinic acid derivatives proceeds thermally with a high degree of stereoselectivity to provide a new route to functionalized pyrrolizidines, indolizidines, or quinolizidines.The ring closure proceeds with simultaneous stereoselective introduction of three or four stereocenters.Molecular mechanics calculations have been refined to accurately predict not only which stereoisomer is preferred but also the syn and anti coupling constants in these tricyclic molecules.