132925-01-0Relevant academic research and scientific papers
Stereoselektive Insertion von Ketenen in O,O-Acetale: Synthese von β-Alkoxyestern und 1,4-Dioxepan-5-onen
Mulzer, Johann,Trauner, Dirk,Bats, Jan W.
, p. 2093 - 2095 (2007/10/03)
Keywords: Acetale; Aldoladditionen; Dioxepanone; Ketene
Efficient Activation of Acetals, Aldehydes, and Imines toward Silylated Nucleophiles by the Combined Use of Catalytic Amounts of 2 and TMS-CN under Almost Neutral Conditions
Soga, Tsunehiko,Takenoshita, Haruhiro,Yamada, Masaaki,Mukaiyama, Teruaki
, p. 3122 - 3131 (2007/10/02)
In the presence of catalytic amount of a transition metal compound such as 2, Co(acac)2, or NiCl2, trimethylsilyl cyanide smoothly reacts with acetals to form α-methoxy carbonitriles in good yields.In the coexistence of catalytic amounts of Rh
