132933-61-0Relevant academic research and scientific papers
Peterson (silyl-Wittig) methylenation of carbonyl compounds using Nafion-H catalyzed hydroxy-trimethylsilane elimination of β-hydroxysilanes
Olah,Reddy,Prakash
, p. 29 - 30 (2007/10/02)
The Peterson (silyl-Wittig) methylenation of carbonyl compounds is significantly improved by convenient hydroxy-trimethylsilane elimination of the intermediate β-hydroxysilanes using perfluoroalkanesulfonic acid (Nafion-H) catalysis. These high yield reactions proceed at room temperature, and the workup involves only filtration of the catalyst.
