13295-59-5Relevant academic research and scientific papers
PHOTOCHEMISTRY OF BIS(2-METHYL-1-PROPENYL)ETHER AND 2,2,4,4-TETRAMETHYL-6-OXABICYCLOHEXAN-3-ONE: ON THE SEARCH FOR THE OXYDI-?-METHANE REARRANGEMENT
Adam, Waldemar,Berkessel, Albrecht,Krimm, Stefan
, p. 619 - 622 (2007/10/02)
?,?*-Excitation of bis(2-methyl-1-propenyl)ether leads to products derived from a vinyl-vinyloxy radical pair; photochemical decarbonylation (n,?*) of the title ketone provides an entry into the diradical manifold of the oxydi-?-methane rearrangement.
Epoxidation of 2,5-Dimethyl-2,4-hexadiene with m-Chloroperbenzoic Acid
Hashem, Md. Abul,Manteuffel, Elfriede,Weyerstahl, Peter
, p. 1267 - 1270 (2007/10/02)
Reaction of 2,5-dimethyl-2,4-hexadiene (1) with equivalent amounts of MCPBA gives mainly the diol monobenzoate 4.In presence of NaHCO3 the monoepoxide 2 is formed in moderate yield, but ring cleavage to 4 can not be totally suppressed.Excess MCPBA in buff
