13296-49-6Relevant articles and documents
10-ALKENYLPHENOTHIAZINES. SYNTHESIS AND MECHANISM OF ACIDIC HYDROLYSIS OF cis- AND trans- 10-(2-PHENYLVINYL)PHENOTHIAZINES
Anfinogenov, V. A.,Napilkova, O. A.,Sirotkina, E. E.,Filimonov, V. D.,Khlebnikov, A. I.
, p. 1152 - 1157 (1986)
The addition of phenothiazine to phenylacetylene in super-base media proceeds regio- and stereoselectively and leads to the predominant formation of cis-10-(2-phenylvinyl)phenothiazine, which is completely converted to its trans-isomer at 200 deg C.Kinetic analysis of the acid hydrolysis of the cis- and trans- isomers has alloved us to assign to it an ACE2 reaction mechanism, similar to the mechanism of hydrolysis of vinyl alkyl ethers.
