132969-36-9

Upstream product

• 105387-01-7 5,5,8aβ-trimethyl-4aα,5,6,7,8,8a-hexahydro-2(1H)-naphthalenone 
• 123298-88-4 (1R,2R,4aR,8aR)-2,5,5,8a-Tetramethyl-1-(tetrahydro-pyran-2-yloxymethyl)-decahydro-naphthalen-2-ol 
• 123298-86-2 1β-<(tetrahydropyranyloxy)methyl>-5,5,8aβ-trimethyl-4aα,5,6,7,8,8a-hexahydro-2(1H)-naphthalenone 
• 123298-86-2 1α-<(tetrahydropyranyloxy)methyl>-5,5,8aβ-trimethyl-4aα,5,6,7,8,8a-hexahydro-2(1H)-naphthalenone 
• 13008-52-1 methyl (+/-)-(1'α,4'aα,8'aβ)-octahydro-5',5',8'a-trimethyl-spiro-<1,3-dioxolane-2,2'(1H)-naphthalene>-1'-carboxylate 
• 73617-03-5 1β-<(tetrahydroxypyranyloxy)methyl>-5,5,8aβ-trimethyl-4aα-octahydro-2(1H)-naphthalenone 
• 52618-00-5 2β-hydroxy-2α,5,5,8aβ-tetramethyl-4aα-decahydro-1β-naphthalenecarbaldehyde 
• 123298-83-9 (+/-)-1-hydroxymethyl-5,5,8a-trimethyl-2-oxodecahydronaphthalene 
• 123298-85-1 1α-hydroxymethyl-5,5,8aβ-trimethyl-4aα,5,6,7,8,8a-hexahydro-2(1H)-naphthalenone 
• 10528-17-3 (+/-)-(1'α,4'aα,8'aβ)-octahydro-5',5',8'a-trimethyl-spiro-<1,3-dioxolane-2,2'(1H)-naphthalene>-1'-methanol 
• 59684-77-4 (+/-)-8-oxo-12-nordriman-11-acid methyl ester 
• 52617-99-9 drimane-8β,11-diol 
• 132969-34-7 α-(2,6-dimethoxy-4-methylphenyl)-2β-hydroxy-2α,5,5,8aβ-tetramethyl-4aα-decahydro-1β-naphthalenemethanol 

Downstream Products

• 132969-37-0 2-(2-{(1S,2R)-2-[(E)-2-(2,6-Dimethoxy-4-methyl-phenyl)-vinyl]-2,6,6-trimethyl-cyclohexyl}-ethyl)-2-methyl-[1,3]dioxolane 

Relevant academic research and scientific papers

1,3-Diol Fragmentation Using a Reactive Benzylic Hydroxyl Group as a Nucleofuge. Synthesis of a Tobacco Sesquiterpene

A benzylic hydroxyl group activated by electron-donative aromatic function was found to be a remarkably reactive nucleofuge for 1,3-diol fragmentation.Thus, treatment of α-(2,6-dimethoxy-4-methylphenyl)-2β-hydroxy-2α,5,5,8aβ-tetramethyl-4aα-decahydro-1β-n

Remarkably Facile 1,3-Diol Fragmentation. Synthesis of a Seco-sesquiterpene of Tobacco

A benzylic hydroxyl group activated by the 2,6-dimethoxy-4-methylphenyl group was proved to be a remarkably reactive nucleofuge in 1,3-diol fragmentation under mild conditions. 4-(2,2,6-Trimethyl-6-vinylcyclohexyl)-2-butanone, a seco-sesquiterpene, was sy