13298-59-4

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 4023-80-7 1-(4-methoxyphenyl)butan-1,3-dione 

Downstream Products

• 1024585-87-2 ethyl 7-(benzyloxy)-1-(1-(4-methoxyphenyl)-2-oxo-propyl)isoquinoline-3-carboxylate 
• 1024585-96-3 ethyl 1-(1-(4-methoxyphenyl)-2-oxo-propyl)benzo[g]isoquinoline-3-carboxylate 
• 1024585-92-9 ethyl 1-(1-(4-methoxyphenyl)-2-oxopropyl)isoquinoline-3-carboxylate 
• 1095874-52-4 ethyl 6-(1-(4-methoxyphenyl)-1-oxopropan-2-yl)-4-methyl-5-phenylpicolinate 
• 1575-08-2 2-methyl-3-(4-methoxyphenyl)-3-oxopropionic acid ethyl ester 
• 40478-63-5 1-p-Methoxyphenyl-2-ethoxy-butan-1,3-dion 
• 5219-08-9 2-(4-methoxyphenyl)acetoacetic acid ethyl ester 

Relevant academic research and scientific papers

Rhodium(ii)-catalysed generation of cycloprop-1-en-1-yl ketones and their rearrangement to 5-aryl-2-siloxyfurans

Donor-acceptor cyclopropenes formed from enoldiazoketones undergo catalytic rearrangement to 5-aryl-2-siloxyfurans via a novel mechanism that involves a nucleophilic addition of the carbonyl oxygen to the rhodium-activated cyclopropene.

A cascade approach to pyridines from 2-Azido-2,4-dienoates and α-diazocarbonyl compounds

A one-pot synthesis of substituted pyridines via a cascade reaction of 2-azido-2,4-dienoates with α-diazocarbonyl compounds and triphenylphosphine is reported. The process involves a Staudinger-Meyer reaction, a Wolff rearrangement, an aza-Wittig reaction, and an electrocyclic ring- closure. The procedure is general and efficient. The substrates are readily available.