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2-Pyrrolidinone, 4-(acetyloxy)-1-(phenylmethyl)-5-(2-propenyl)-, (4S,5R)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 133005-22-8 Structure
  • Basic information

    1. Product Name: 2-Pyrrolidinone, 4-(acetyloxy)-1-(phenylmethyl)-5-(2-propenyl)-, (4S,5R)-
    2. Synonyms:
    3. CAS NO:133005-22-8
    4. Molecular Formula: C16H19NO3
    5. Molecular Weight: 273.332
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 133005-22-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-Pyrrolidinone, 4-(acetyloxy)-1-(phenylmethyl)-5-(2-propenyl)-, (4S,5R)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-Pyrrolidinone, 4-(acetyloxy)-1-(phenylmethyl)-5-(2-propenyl)-, (4S,5R)-(133005-22-8)
    11. EPA Substance Registry System: 2-Pyrrolidinone, 4-(acetyloxy)-1-(phenylmethyl)-5-(2-propenyl)-, (4S,5R)-(133005-22-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 133005-22-8(Hazardous Substances Data)

133005-22-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 133005-22-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,3,0,0 and 5 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 133005-22:
(8*1)+(7*3)+(6*3)+(5*0)+(4*0)+(3*5)+(2*2)+(1*2)=68
68 % 10 = 8
So 133005-22-8 is a valid CAS Registry Number.

133005-22-8Downstream Products

133005-22-8Relevant articles and documents

N-trialkylsilyl Bistrifluoromethanesulfonimides (R3SiNTf 2) are powerful catalysts for the highly efficient α-amido alkylation reactions of silicon-based nucleophiles

Othman, Raja Ben,Bousquet, Till,Othman, Mohamed,Dalla, Vincent

, p. 5335 - 5337 (2007/10/03)

(Chemical Equation Presented) In situ formed N-trialkylsilyl bistrifluoromethanesulfonimides (R3SiNTf2) species have been shown to efficiently catalyze the nucleophilic substitution reactions of chiral 5-oxypyrrolidin-2-ones by silic

Toward improving the chemistry of N-acyliminium ions: Nucleophilic substitution reactions of pyrrolidinone derivatives with trialkylsilyl nucleophiles catalyzed by triisopropylsilyltrifluoromethane sulfonate (TIPSOTf)

Othman, Raja Ben,Bousquet, Till,Fousse, Anthony,Othman, Mohamed,Dalla, Vincent

, p. 2825 - 2828 (2007/10/03)

(Chemical Equation Presented) Nucleophilic substitution reactions of racemic and chiral 5-acetoxy-, 5-ethoxy-, and 5-methoxypyrrolidin-2-ones by silicon-based nucleophiles were efficiently catalyzed by TIPSOTf. This process was found to be general and acc

Addition of silylated carbon nucleophiles to iminium and cyclic N-acyliminium ions promoted by InCl3

Russowsky,Petersen,Godoi,Pilli

, p. 9939 - 9942 (2007/10/03)

InCl3 was used as Lewis acid in the addition of silyl enolates and allyltrimethylsilane to aromatic aldimines and cyclic N-acyliminium ions derived from 5-acetoxylactams affording β-aminocarbonyl systems and allyl adducts, respectively, in reas

SYNTHESIS OF STATINE FROM (S)-MALIC ACID; STEREOCONTROL VIA RADICAL CYCLIZATION

Koot, Wim-Jan,Ginkel, Roel van,Kranenburg, Mirko,Hiemstra, Henk,Louwrier, Saskia,et al.

, p. 401 - 404 (2007/10/02)

Highly stereoselective syntheses of enantiomerically pure γ-amino acids statine and 4-epi-statine from (S)-malic acid are described by using, respectively, an intramolecular α-acylamino radical reaction and an intermolecular N-acyliminium allylsilane coupling.

Stereoselective synthesis of statin analogues

Bernardi,Micheli,Potenza,Scolastico,Villa

, p. 4949 - 4952 (2007/10/02)

Statin analogues can be synthesized stereoselectively (diastereomeric ratios up to 4:1) starting from malic acid. The key step involves an unprecedented cis-selective allylation of an α-alkoxy N-acyliminium ion.

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