1330165-48-4Relevant academic research and scientific papers
Solvent free synthesis of trifluoromethyl tertiary alcohols by cross Aldol reaction
Tao, Rui,Yin, Xue-Jiao,Wang, Ke-Hu,Niu, Yu-Zhuo,Wang, Ya-Lin,Huang, Dan-Feng,Su, Ying-Peng,Wang, Jin-Xian,Hu, Yu-Lai,Fu, Ying,Du, Zheng-Yin
, p. 1046 - 1049 (2015)
Abstract Exceedingly fast preparation of trifluoromethyl tertiary alcohols has been accomplished from methyl ketones and trifluoromethyl ketones under solvent free conditions by cross Aldol reaction. The reaction was achieved in the presence of common ino
Copper-Catalyzed Aldol Reaction of Vinyl Azides with Trifluoromethyl Ketones
Liu, Zhenhua,Zhang, Zhihai,Zhu, Guangyu,Zhou, Yiqin,Yang, Lin,Gao, Wen,Tong, Lili,Tang, Bo
supporting information, p. 7324 - 7328 (2019/10/08)
A novel and efficient aldol reaction of readily available vinyl azides with trifluoromethyl ketones by copper catalysis is developed. The reaction is proposed to go through a nucleophilic trapping of vinyl azides with trifluoromethyl ketones as a trifluor
Direct aldol reaction of trifluoromethyl ketones with ketones catalyzed by Et2Zn and secondary amines
Sasaki, Shigeru,Kikuchi, Kasumi,Yamauchi, Takayasu,Higashiyama, Kimio
supporting information; experimental part, p. 1431 - 1434 (2011/08/03)
The direct catalytic aldol reaction of trifluoromethyl ketones with ketones has been accomplished. The reaction was achieved in the presence of 10 mol% Et2Zn and N,N-dimethylethylenediamine at ambient temperature to give the expected aldol-type
