1330184-03-6Relevant articles and documents
Development and Application of Pyridinium 1,4-Zwitterionic Thiolates: Synthesis of Polysubstituted Thiophenes
Cheng, Bin,Duan, Xiaoguang,Li, Hui,Li, Yun,Li, Yuntong,Wang, Taimin,Wu, Fufang,Zhai, Hongbin,Zhang, Xinping
, (2020)
Pyridinium 1,4-zwitterionic thiolates as a class of sulfur-containing synthons were applied to a [3+2] cascade cyclization reaction with activated alkynes, affording a library of polysubstituted thiophenes with excellent regioselectivities, especially those bearing various fluorine-containing groups. The freshly disclosed pyridinium 1,4-zwitterionic thiolates decorated with acyl or trifluoromethyl groups exhibited powerful potential in the synthesis of polysubstituted thiophenes. Of particular note is that pyridinium A4 could introduce sulfur and CF3 groups to target products simultaneously.
One-pot two-component [3 + 2] cycloaddition/annulation protocol for the synthesis of highly functionalized thiophene derivatives
Nandi, Ganesh Chandra,Samai, Subhasis,Singh, Maya Shankar
supporting information; experimental part, p. 8009 - 8014 (2011/12/01)
An efficient and experimentally rapid protocol for the synthesis of hitherto unreported 2,3-dicarboalkoxy-4-aroyl/heteroaroyl/alkanoyl thiophenes has been developed via 1 - 2 (C - S) and 3 - 4 (C - C) bond connections promoted by 4-dimethylaminopyridine (