133030-48-5

Basic information

• Product Name: (2RS,3SR)-2,6-dimethylphenyl 3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propionate
• CAS NO: 133030-48-5
• Molecular Weight: 380.551
• Mol File: 133030-48-5.mol

Chemical Properties

• CAS DataBase Reference: (2RS,3SR)-2,6-dimethylphenyl 3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: (2RS,3SR)-2,6-dimethylphenyl 3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propionate(133030-48-5)
• EPA Substance Registry System: (2RS,3SR)-2,6-dimethylphenyl 3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propionate(133030-48-5)

Safety Data

• Hazardous Substances Data: 133030-48-5(Hazardous Substances Data)

Upstream product

• 104750-38-1 (2RS,3SR)-2,6-dimethylphenyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 

Relevant articles and documents

PHENYLTHIO(PhS) MIGRATION IN THE STEREOCONTROLLED SYNTHESIS OF ALLYLIC ALCOHOLS WITH 1,4 RELATED CHIRAL CENTRES.

Stereoselective aldol products are transformed by PhS migration into lactones, tetrahydrofurans, and, by subsequent Evans-Mislow rearrangement, into the title compounds with complete stereochemical control.

Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres

syn- and anti-Selective aldol reactions between enolates of propionate esters and three α-phenylthio cycloalkanecarbaldehydes give single diastereoisomers of phenylthio alcohols which rearrange in acid with 5-hydroxy or 5-CO2H participation to give spiroc