133043-04-6

Basic information

• Product Name: (+)-methyl <5R,(S)R>-5-<(tert-butyldimethylsilyl)oxy>-6-(p-tolylsulfinyl)hexanoate
• Synonyms: (+)-methyl <5R,(S)R>-5-<(tert-butyldimethylsilyl)oxy>-6-(p-tolylsulfinyl)hexanoate
• CAS NO: 133043-04-6
• Molecular Weight: 398.639
• Mol File: 133043-04-6.mol

Chemical Properties

• CAS DataBase Reference: (+)-methyl <5R,(S)R>-5-<(tert-butyldimethylsilyl)oxy>-6-(p-tolylsulfinyl)hexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-methyl <5R,(S)R>-5-<(tert-butyldimethylsilyl)oxy>-6-(p-tolylsulfinyl)hexanoate(133043-04-6)
• EPA Substance Registry System: (+)-methyl <5R,(S)R>-5-<(tert-butyldimethylsilyl)oxy>-6-(p-tolylsulfinyl)hexanoate(133043-04-6)

Safety Data

• Hazardous Substances Data: 133043-04-6(Hazardous Substances Data)

Upstream product

• 108-55-4 glutaric anhydride, 
• 133043-10-4 5-oxo-6-(p-tolylsulfinyl)hexanoic acid 
• 133043-02-4 (+)-methyl <(S)R>-5-oxo-6-(p-tolylsulfinyl)hexanoate 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 
• 133043-03-5 (+)-methyl <5R,(S)R>-5-hydroxy-6-(p-tolylsulfinyl)hexanoate 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 10497-40-2 2,4-Dimethoxy-zearalenone 
• 133043-08-0 (+)-(1'E,10'S)-2,4-dimethoxy-6-<10'-hydroxy-6',6'-(trimethylenedithio)-1'-undecenyl>benzoic acid 
• 133043-07-9 (+)-methyl (1'E,10'S)-2,4-dimethoxy-6-<10'-hydroxy-6',6'-(trimethylenedithio)-1'-undecenyl>benzoate 
• 133043-06-8 (+)-methyl (1'E,10'S)-2,4-dimethoxy-6-<10'-<(tert-butyldimethylsilyl)oxy>-6'-oxo-1'-undecenyl>benzoate 
• 133043-05-7 methyl (1'E,10'S)-2,4-dimethoxy-6-<10'-<(tert-butyldimethylsilyl)oxy>-6'-oxo-5'-(p-tolylsulfonyl)-1'-undecenyl>benzoate 

Relevant articles and documents

Asymmetric Synthesis of (S)-Zearalenone Dimethyl Ether, an Orsellinic Acid Type Macrolide

The synthesis of (S)-zearalenone dimethyl ether is described.The chiral part of the molecule was obtained by asymmetric synthesis monitored by a chiral sulfoxide group and introduced in the very last steps of the synthesis.