13316-70-6Relevant articles and documents
Three-dimensional mesoporous gallosilicate with Pm3n symmetry and its unusual catalytic performances
Srinivasu, Pavuluri,Vinu, Ajayan
, p. 3553 - 3561 (2008)
Three-dimensional, mesoporous-cage-type, GaSBA-1 materials with different nSi/NGa ratios have been successfully prepared for the first time by using a low hydrochloric acid to silicon (nHCl/n Si) molar ratio in
Effect of Head-Group Size on Micellization and Phase Behavior in Quaternary Ammonium Surfactant Systems
Buckingham, Scott A.,Garvey, Christopher J.,Warr, Gregory G.
, p. 10236 - 10244 (1993)
The micellization and phase equilibria in aqueous solutions of cationic quaternary ammonium bromide surfactants of the type alkyltrimethyl-, -ethyl-, -propy-, -butyl-, and -pentylammonium bromide have been investigated as a function of alkyl chain length, electrolyte concentration, and temperature.A large isotropic (micellar) phase is observed in triethyl- and tripropylammonium surfactants, which demixes into two conjugate phases on warming in the case of the alkyltributylammonium bromides.Liquid-liquid phase separation is also observed for tetradecyltripentylammonium bromide.Critical micelle concentrations are found to decrease with increasing hydrophobicity of the surfactant ion, but the free energy of micellization of tetradecyltributylammonium bromide is the same as that of tetradecyltrimethylammonium bromide over a range of temperatures.Some evidence is found for the formation of premicellar aggregates in tributylammonium surfactants at elevated temperatures, consistent with significant polydispersity and changing monomer concentrations observed previously.The results are discussed in terms of the hydrophobic and electrostatic contributions of the free energy of micellization, and some interferences are drawn regarding the nature of the interactions which give rise to phase separation.
In situ NMR and XRD studies of the growth mechanism of SBA-1
Egger,Anderson,Tiddy,Casci
, p. 1845 - 1855 (2005)
In situ 17O, 14N and 29Si nuclear magnetic resonance (NMR) coupled with in situ energy dispersive X-ray diffraction (EDXRD) have been used to investigate the growth of the siliceous mesoporous material, SBA-1, synthesised
Acetalization of heptanal over Al-SBA-1 molecular sieve
Venkatachalam,Palanichamy,Murugesan
body text, p. 299 - 303 (2011/07/31)
Al-SBA-1 (Si/Al = 40, 80 and 120) and Al,Mg-SBA-1 (Si/(Al + Mg) = 40 and 80) molecular sieves were synthesized and characterized. Acetalization of n-heptanal with methanol was studied under autogenous pressure between 80 and 150 °C. Since protonation of n