1331733-52-8Relevant articles and documents
Metal-free SN2a′ decarboxylative rearrangement of β-keto esters
Bizet, Vincent,Lefebvre, Valerie,Baudoux, Jerome,Lasne, Marie-Claire,Boulange, Agathe,Leleu, Stephane,Franck, Xavier,Rouden, Jacques
, p. 4170 - 4175 (2011/10/02)
Treatment of 2-methoxycarbonyl-(or 3-cyano-)allyl acetoacetates with a tertiary amine or triphenylphosphane afforded α-methylene γ-substituted δ-keto esters (or nitrile) in satisfactory yields. Various bases and nucleophiles were tested to elucidate the m