1331753-76-4Relevant academic research and scientific papers
Metal-induced phosphorescence in (Pentafluorophenyl)gold(III) complexes
Bojan, Vilma R.,Lopez-De-Luzuriaga, Jose M.,Manso, Elena,Monge, Miguel,Olmos, M. Elena
, p. 4486 - 4489 (2011/11/01)
The complexes [Au(C6F5)2(4-X-Py) 2]ClO4 (X = CN (1), H (2), CH3 (3)) and [Au(C6F5)Cl2(4-X-Py)] (X = CN (4), H (5), CH3 (6)) have been synthesized. The crystal structure of complexes 1, 3?0.5Et2O, 4, and 5 have been determined by X-ray diffraction methods. The photophysical behavior of all complexes has been studied experimentally through UV/vis spectroscopy and photoluminescence studies. TD-DFT calculations and full optimization of the ground state (S0) and lowest triplet excited state (T1) have been carried out in order to assign the photophysical properties of the complexes.
